 หัวเรื่อง:ไม่มีชื่อไทย (ชื่ออังกฤษ : Complexation and Spectrophotometric Determination of Cobalt(II) Ion with 3-(2?-thiazolylazo)-2,6-diaminopyridine) ผู้เขียน: Natthapon VEERACHALEE, Pongpol Taweema, ดร.อภิสิฏฐ์ ศงสะเสน, รองศาสตราจารย์ สื่อสิ่งพิมพ์:pdf AbstractThe complexation of 3-(2?-thiazolylazo)-2,6-diaminopyridine (TADAP) with cobalt(II) has been studied spectrophotometrically. The stability constant of TADAP ligand with cobalt(II) ion has been determined at a constant temperature, where the molar ratio of this complex is 1:2 (metal:ligand). TADAP has been prepared and characterized on the basis of FT-IR spectral data. A procedure for the spectrophotometric determination of this complex is proposed where it is rapid, sensitive and highly specific. Beer’s law was obeyed in the range 2.0 ? 10-6-1.2 ? 10-5 M at pH 10 to form a green complex. The limit of detection is 5.26 ? 10-7 M (? = 1.52 ? 104 l-1mol-1cm-1 at ?max = 598 nm). |
 |
 |